X-ray Energy-Dispersive Spectrometry During In Situ Liquid Cell Studies Using an Analytical Electron Microscope

Zaluzec, Nestor J., M. Grace Burke, Sarah J. Haigh and Matthew A. Kulzick, 2014

Abstract

The use of analytical spectroscopies during scanning/transmission electron microscope (S/TEM) investigations of micro- and nano-scale structures has become a routine technique in the arsenal of tools available to today’s materials researchers. Essential to implementation and successful application of spectroscopy to characterization is the integration of numerous technologies, which include electron optics, specimen holders, and associated detectors. While this combination has been achieved in many instrument configurations, the integration of X-ray energy-dispersive spectroscopy and in situ liquid environmental cells in the S/TEM has to date been elusive. In this work we present the successful incorporation/modifications to a system that achieves this functionality for analytical electron microscopy.

Impact Statement

This paper describes results using a modified Poseidon 200 in situ TEM holder to optimize X-ray energy dispersive spectroscopy (EDS) of specimens in liquid by improving the line of sight from the specimen to the EDS detector.
Keywords: Nanoparticles; EDS