Real-time imaging of lead nanoparticles in solution – determination of the growth mechanism

Diana L. Delach, Madeline J. Dukes, A. Cameron Varano, Deborah F. Kelly, Albert D. Dukes III, 2015
lead nanoparticle growth capture in situ
Image courtesy of RSC Advances

Abstract

In situ electron microscopy is a tool which offers great promise for studying the mechanisms responsible for nanoparticle growth. In aqueous solution, the reduction of Pb2+ by the electron beam results in the formation of lead nanoparticles. Here, we directly examined the fundamental processes that influence the growth of lead nanoparticles in solution using in situ transmission electron microscopy. Lead nanoparticle growth was directly monitored at the molecular level and followed the sequence of nucleation, Ostwald ripening, and aggregative growth. The aggregative growth phase resulted in macrostructures having micron-sized dimensions. Importantly, when combined with quantitative measurements, our direct imaging results suggested that the growth properties observed for lead nanoparticles were unique in comparison to other metallic entities.

Impact Statement

Electron-beam induced growth of lead nanoparticles from a solution of lead nitrate using a 120 KV acceleration voltage.  A two-phase growth mechanism was observed after the initial particle nucleation:  oswaldt ripening followed by aggregative growth resulting in the formation of micron-scale particles.